×

Carpathian Journal of Earth and Environmental Sciences

An International Peer-Reviewed Open Access Journal

Indexed in Scopus SCIE (Web of Science) Crossref GeoRef

« Back

ARTICLE IN » Volume 5, 2010 - Number 2

SORPTION OF COPPER AND LEAD ON SOILS AND SOIL CLAY FRACTIONS WITH DIFFERENT CLAY MINERALOGY



Péter SIPOS
Institute for Geochemical Research, Hungarian Academy of Sciences, H-1112 Budapest, Budaörsi út 45., Hungary,
e-mail: sipos@geochem.hu

Reading time: | words
Download PDF document Downloads: 6940

Abstract

There are numerous results on the characteristics of metal sorption by total soil samples or soil clay fractions separately. However, not many have focused on the comparison of these characteristics of total soil and clay fraction samples from the same soil. In this study Cu and Pb batch sorption experiments were carried out on samples from the genetic horizons of two Luvisol profiles characterized by vermiculite and montmorillonite as dominant clay minerals, respectively. Freundlich KF and n parameters for Cu and Pb sorption on the total soil samples unanimously show the primary role of the soil organic matter, as well as the preference of vermiculite over montmorillonite in the retention of both metals. These results were effectively completed by those from the experiments performed on soil clay fractions. It was shown that the generally higher affinity of Pb than Cu to the studied soils is primarily due its very strong affinity to the soil organic components. Additionally, in the studied acidic-slightly acidic Luvisol samples sorption of Pb on clay surfaces seems to be much more inhibited when compared to Cu. Consequently, combined study of sorption properties of total soil samples and soil clay fractions helps us in better understanding the sorption process of potentially toxic metals in soils.
Keywords:
  • potentially
  • toxic
  • metals
  • vermiculite
  • montmorillonite
  • Freundlich
  • curve
  • Luvisol

Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of CJEES and/or the editor(s). CJEES and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

© 2010 by the author(s). Licensee CJEES, Carpathian Association of Environment and Earth Sciences. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).

How to cite

Péter SIPOS (2010). SORPTION OF COPPER AND LEAD ON SOILS AND SOIL CLAY FRACTIONS WITH DIFFERENT CLAY MINERALOGY

Google Scholar
Loading...

Checking for open citations...